LP 1

1. Main Title and Closing Theme
2. The Corbomite Maneuver: Radiation/Cube Radiation/Baby Balok/Fesarius Approaches
3. Charlie X: Kirk's Command/Charlie's Mystery/Charlie's Gift
4. Charlie X: Kirk Is Worried/Card Tricks/Charlie's Yen
5. Charlie X: Zap Sam/Zap Janice/Zap the Cap/Zap the Spaceship
6. Charlie X: Charlie's Friend/Goodbye Charlie/Finale
7. The Doomsday Machine: Goodbye M. Decker/Kirk Does It Again
8. Mudd's Women: Three Venuses/Meet Mr. Mudd/Hello Girls/Venus Aboard/Mudd Laffs
9. Mudd's Women: Hello Ruth/The Last Crystal/The Venus Drug
10. Mudd's Women: Planet Rigel/Eve Is Out/Space Radio
11. Mudd's Women: Eve Cooks/Pretty Eve/Mudd's Farewell

LP 2

1. Main Title and Closing Theme
2. By Any Other Name: Neutralizer/Kelvan Theme/More Neutralizers/Broken Blocks
3. By Any Other Name: Rojan's Revenge/Rojan's Blocks/Pretty Words/Rojan's Victory/Finale
4. The Trouble With Tribbles: A Matter of Pride/No Tribble at All/Big Fight
5. Mirror, Mirror: Mirror, Mirror/Black Ship Theme/The Agonizer/Meet Marlena
6. Mirror, Mirror: Black Ship Tension/Goodbye Marlena/Short Curtain
7. The Empath: Enter Gem/Kirk Healed
8. The Empath: Vian Lab/The Subjects/Cave Exit/Star Trek Chase
9. The Empath: Help Him/Spock Stuck/McCoy Tortured
10. The Empath: Time Grows Short
11. The Empath: Vian's Farewell/Empath Finale